updated 10/17/2012 AT 11:00 AM ET
•originally published 10/17/2012 AT 5:00 PM ET
Art imitates life!
The newlywed, 25, was snapped donning a gold and cream Georges Chakra Couture strapless gown on the set of Gossip Girl on Tuesday, as she stood opposite costar Penn Badgley.
“[It was a] charming, charming wedding,” Stewart said.
“Real people, real love. Just really nice [and] personal, which I think is what a wedding must and should be,” she added.